2-Amino-4,6-dimethylpyridinium benzoate
نویسندگان
چکیده
In the title compound, C(7)H(11)N(2) (+)·C(7)H(5)O(2) (-), the 2-amino-4,6-dimethyl-pyridinium cation and the benzoate anion are linked by two N-H⋯O hydrogen bonds, forming an R(2) (2)(8) ring motif. The H atoms in both the methyl groups are rotationally disordered, with fixed site occupancies of 0.50. In the crystal structure, the mol-ecules are stabilized by inter-molecular N-H⋯O hydrogen bonds. A π-π inter-action, with a centroid-centroid distance of 3.661 (2) Å, is also observed.
منابع مشابه
2-Amino-4,6-dimethylpyridinium chloride dihydrate
In the title hydrated mol-ecular salt, C(7)H(11)N(2) (+)·Cl(-)·2H(2)O, the pyridine N atom of the 2-amino-4,6-dimethyl-pyridine mol-ecule is protonated. The cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, the components are linked by N-H⋯O, N-H⋯Cl and O-H⋯Cl hydrogen bonds, thereby forming sheets lying parallel to (100). The crystal structure is further st...
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